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Boiler Water-Problems and Solutions Course Content

Writer's picture: Vidhya ShreeVidhya Shree

If you're in the market for boiler water treatment, you need to understand what chemicals are used. This is crucial if you want to reduce deposits. You should also know the limits of impurities and how to identify chemical changes. This course will provide you with the knowledge you need to get the most out of your boiler water treatment system.

Chemicals used in boiler water treatment

Boiler water treatment chemicals are used in boilers to reduce the oxygen content in feedwater and prevent corrosion within the boiler and turbine. These substances are delivered into the feedwater through injection equipment. These chemicals also help to maintain the purity of the feedwater. One of the most common types of chemicals is sodium sulfite, a nonvolatile oxygen scavenger. It reduces dissolved oxygen and adds inorganic dissolved solids to the feedwater.

Chemicals used in boiler water treatment vary depending on the type of boiler and its operating conditions. The chemicals used to treat boiler water must be approved by federal statute and are designed to eliminate various types of contaminants from the water. Some common chemicals used in boiler water treatment include alkalinity and amines, which help maintain a pH level of 10.5 for condensing boilers. Other chemicals are phosphates, which sink calcium to the bottom of the boiler and allow it to escape through the blowdown valve. In addition, sulfites are used to remove dissolved oxygen from the water. Dissolved oxygen is extremely harmful to boiler systems and can cause a wide range of damage.

Some chemicals are specifically designed to remove precipitated hardness from boiler water. These chemicals are made from long chain organic molecules that carry a slight negative electrical charge. These chemicals help protect iron, copper, and brass boilers, as well as central heating systems.

Limits for impurities

Boiler water and steam quality are critical to the availability and reliability of power plant components. To help power plants achieve these goals, EPRI has been investigating the partitioning process of impurities in the water and steam that feed their boilers. Impurities that are carried over to the turbine steam are mostly vapors or mechanically dissolved solids. Some of these impurities form scale when heated, while others are non-scale-forming. To make boiler water and steam compositions more consistent and reliable, a rigorous new approach is needed.

Impurities can cause boiler water and steam system problems and may even lead to boiler system failure. Because of these risks, impurity levels are regulated to prevent failure of the boiler. This is done through designated limits for impurities in boiler water and steam. If the feedwater does not meet these limits, it must be pretreated.

One of the most common methods of boiler water treatment is the use of chelants, which are weak organic acids injected into boiler feedwater. These chemicals are hydrolyzed by the water, and the chelant's chemical properties are affected by the pH. The most effective chelants, EDTA and NTA, are those that are both stable and water-soluble and do not precipitate.

Cost of chemicals

The cost of chemicals in boiler water is a major consideration when designing a boiler water treatment program. While chemicals are a small portion of the overall operating cost of a boiler, they play a vital role in the overall water balance of a boiler. This is important because chemicals in boiler water can have a negative impact on the boiler's overall efficiency. An effective water treatment program can lower the overall chemical cost of a boiler by one to two percent, which can save the company thousands of dollars a year.

Several chemicals are available for boiler water treatment, including oxygen scavengers and alkalinity boosters. These chemicals reduce dissolved oxygen and oxides and passivate metal surfaces.

Identifying changes in boiler chemistry

Boiler combustion is a complex process that produces high concentrations of steam and water. The water enters the boiler through the burner and downcomer, where it is heated and condensed to generate steam. The heat generated causes the water to boil, and the steam is then expelled through the generating tubes. Increasing the amount of heat applied to the fire tube will result in more steam production and less water loss. The process also results in deposits that resist the flow and reduce circulation.

Chemicals that act as softening agents are used to reduce the buildup of scale inside boilers. This scaling can be a significant problem and cause boilers to become less efficient. As the scale grows, the harder impurities become concentrated and will stick to the boiler surfaces. This can lead to a number of problems, including water hammer.

One of the first steps to improve boiler performance is to identify any changes in boiler water chemistry. The presence of phosphate is easy to detect, and the presence of chelant makes it possible to test the efficacy of the treatment. It also helps to reduce the amount of impurities in boiler water.


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